![]() Amides (and Lactams) + H2O -> ? (acid-catalyzed vs.Esters (and Lactones) + H2O -> ? (acid-catalyzed vs.Relative Reactivities of Carboxylic Acid DerivativesĢ0-9 - Hydrolysis Reactions (Addition of H2O).Tetrahedral Intermediates, Reaction Rates, and Relative Stabilities.The Mechanism of Acyl Substitution Reactions Under Acidic Conditions Because of their reactivity and the ease with which they can be prepared from carboxlylic acids, acyl chlorides are the most commonly used starting materials.The Mechanism of Acyl Substitution Reactions Under Basic Conditions.IR Spectroscopy of Acid Anhydrides (asymmetric stretch & symmetric stretch)Ģ0-8 - Reactions of Carboxylic Acid Derivatives (BIG TOPIC) – thru p.20-26.Esters Prefer to be Planar (Z-conformation vs. As a consequence of these reactivity differences, its usually possible to convert a more reactive acid derivative into a less reactive one.Substituents (“Branches”)Ģ0-5 - Structures, Properties, & Spectrosopy of Carboxylic Acid Derivatives ![]() Esters: Straight-Chained Esters and Cyclic Esters (“Lactones”)Ģ0-5 - Priority Order of Principle Groups in Carboxylic Acid Derivatives.SECTION 20 – Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution ReactionsĢ0-1 - General Classes and Nomenclature of Carboxylic Acid Derivatives 3 - Chemical Quantities and StoichiometryĤ - Types of Chemical Reactions and Solution Stoichiometryħ - Quantum Mechanical View of the Atom, and Periodicityĩ - Covalent Bonding and Molecular Orbitalsġ0 - Liquids, Solids, and Intermolecular Forcesġ5 - Applications of Acid-Base Equilibriaġ6 - Spontaneity, Entropy, and Free Energyġ8 - Transition Metals and Coordination ChemistryĢ0 - An Introduction to Organic Chemistryġ - Structural, Bonding, Molecular PropertiesĢ - The Nature of Organic Compounds: Alkanes and Cycloalkanesģ - Stereochemistry of Alkanes and Cycloalkanes: 3-D Structures of MoleculesĤ - The Study of Organic Reactions: An Overviewġ0 - Substitution (SN2, SN1) and Elimination (E2, E1) Reactionsġ1 - Mass Spectrometry and IR Spectroscopyġ3 - Conjugated Systems and UV Spectroscopyġ5 - Electrophilic Aromatic Substitution (E.A.S.)ġ8 - Aldehydes and Ketones: Nucleophilic Addition ReactionsĢ0 - Carboxylic Acid Derivatives and Nucleophilic Acyl Substitution ReactionsĢ1 - Carbonyl Alpha-Substitution ReactionsĬarboxylic Acid Derivatives and Nucleophilic Acyl Substitution Reactions - Section 20 of Organic Chemistry Notes is 27 pages in length (page 20-1 through page 20-27) and covers ALL you'll need to know on the following lecture/book topics: The carboxylic acids, acid halides, and esters are reduced to alcohols, while the amide derivative is reduced to an amine.
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